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While pottery may seem like a simple art of shaping clay into forms, there’s actually a fascinating science behind the materials and processes involved. From the molecular structure of the clays themselves to the complex physics of firing, having a deeper understanding of these principles can help potters improve their skills and productions. Let’s dive into the scientific makeup of pottery.

The Chemistry of Clay
At its most basic level, clay is a natural earthy material composed of one or more clay minerals and traces of metal oxides and organic matter. The primary minerals in clay are aluminum phyllosilicate minerals like kaolinite, montmorillonite, and illite.

These plate-like clay particles have a unique crystalline structure with an outer negatively charged surface surrounded by positively charged edges. When mixed with water, this allows the flat particles to stack together and form a dense, plastic and moldable mass perfect for shaping pottery.

Clay Bodies: Plastic vs. Drying Properties
Different types of clay bodies are formulated for different properties during the plastic/workable state versus the drying/firing states. Clays with larger particle sizes like grogged or groggy clay bodies stay more rigid when shaped, while smoother finer clay particles increase plasticity and malleability.

The mineral makeup also impacts ceramics during drying. Kaolinitic clays have a low particle charge, meaning less ionic bonding between particles, so they dry quickly with reduced shrinkage and warping. In contrast, montmorillonite’s high charge leads to more particle bonding for higher plasticity but increased shrinkage.

The Heat Work
Once pieces have been shaped, pottery undergoes two crucial firing phases in the kiln: bisque firing and glaze firing. During the bisque, chemically bonded water molecules are driven out of the clay’s structure through heat up to 1832°F. This vitrification process hardens the clay body through the formation of aluminum silicate glass.

For most ceramics, a second firing at an even higher temperature around 2372°F melts the glaze coating into a glassy substance that vitrifies and seals the clay surface. Complex thermal dynamics take place as glazes with different coefficients of expansion melt and fuse with clay bodies.

Glaze Chemistry
The composition of ceramic glazes is calculated through precise chemistry to create everything from vibrant colors and special effects to durable surfaces. Glaze recipes utilize fluxes like silica that melts easily into glass, stabilizers like aluminum oxide that make glazes more viscous, and colorants like cobalt carbonate for beautiful blue hues.

Understanding the molecular interactions between the clay and glaze during heating and cooling cycles in the kiln is critical for quality ceramics. Elements like quartz can undergo structural changes that cause issues like crazing (glaze cracking).

From working properties of clay bodies to firing cycles and glaze applications, the science behind pottery encompasses a wide range of chemical and physics processes. With experience and knowledge of these core scientific principles, potters can elevate their ceramic art to new levels.